TETRAMETHYLGUANIDINIUM AZIDE AS A NEW REAGENT FOR THE STEREOSELECTIVESYNTHESIS OF GLYCOSYL AZIDES

Authors
LI C ARASAPPAN A FUCHS PL
Citation
C. Li et al., TETRAMETHYLGUANIDINIUM AZIDE AS A NEW REAGENT FOR THE STEREOSELECTIVESYNTHESIS OF GLYCOSYL AZIDES, Tetrahedron letters, 34(22), 1993, pp. 3535-3538
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
22
Year of publication
1993
Pages
3535 - 3538
Database
ISI
SICI code
0040-4039(1993)34:22<3535:TAAANR>2.0.ZU;2-R
Abstract
Tetramethylguanidinium azide was used in the quantitative conversion o f glycosyl halides 1 - 6 to the corresponding glycosyl azides 7 - 12. The stereoselective reactions occurred with complete inversion at the anomeric centers.