ONE-ELECTRON TRANSFER-REACTION OF PHENYL VINYL SULFIDES WITH DIOXYGEN- THE FATE OF THE INTERMEDIATE VINYL SULFIDE RADICAL CATIONS

Authors
BENATI L MONTEVECCHI PC NANNI D SPAGNOLO P
Citation
L. Benati et al., ONE-ELECTRON TRANSFER-REACTION OF PHENYL VINYL SULFIDES WITH DIOXYGEN- THE FATE OF THE INTERMEDIATE VINYL SULFIDE RADICAL CATIONS, Tetrahedron letters, 34(22), 1993, pp. 3595-3598
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
22
Year of publication
1993
Pages
3595 - 3598
Database
ISI
SICI code
0040-4039(1993)34:22<3595:OTOPVS>2.0.ZU;2-Z
Abstract
Mild reaction of pheyl vinyl sulfides with dioxygen can lead to the ev entual formation of rearranged vinyl sulfides and/or carbonyl-containi ng sulfide products, which are believed to result from decomposition o f initially-formed vinyl sulfide radical cations. Supporting evidence is provided by the comparable findings obtained from the one electron oxidation of one vinyl sulfide by cerium (IV) ammonium nitrate.