BORON CHELATE COMPLEXES WITH (R-PYRID-2-YL)CARBAMOYL]-3-AMINO-2-CYANOBUTEN-2-IC ACID-ESTERS (CODIMERS OF N-(R-PYRID-2-YL)AMIDES AND THE ETHYL-ESTER OF CYANOACETIC ACID)
Vs. Bogdanov et al., BORON CHELATE COMPLEXES WITH (R-PYRID-2-YL)CARBAMOYL]-3-AMINO-2-CYANOBUTEN-2-IC ACID-ESTERS (CODIMERS OF N-(R-PYRID-2-YL)AMIDES AND THE ETHYL-ESTER OF CYANOACETIC ACID), Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(9), 1992, pp. 1693-1699
Mono- and binuclear boron chelates have been synthesized by the action
of butylthiodibutylborane on the ethyl esters of (R-pyrid-2-yl)carbam
oyl]-3-amino-2-cyanobuten-2-ic acids (codimers of N-(R-pyrid-2-yl) ami
des and the ethyl ester of cyanoacetic acid). Complexes of this type c
an exist in solution in the form of two tautomers: acetamide acid deri
vatives or the corresponding ketene N,O-acetals.