SYNTHESIS AND STRUCTURE OF 1-SUBSTITUTED 1-OXO-1,2-DIHYDRO-4H-3,1-BENZOXAPHOSPHORINS

Authors
BOVIN AN CHEKHLOV AN TSVETKOV EN
Citation
An. Bovin et al., SYNTHESIS AND STRUCTURE OF 1-SUBSTITUTED 1-OXO-1,2-DIHYDRO-4H-3,1-BENZOXAPHOSPHORINS, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(9), 1992, pp. 1704-1708
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
9
Year of publication
1992
Part
2
Pages
1704 - 1708
Database
ISI
SICI code
1063-5211(1992)41:9<1704:SASO11>2.0.ZU;2-W
Abstract
1-X-1-Oxo-1,2-dihydro-4H-3,1-benzoxaphosphorins (X = CH2Cl, Ph, and OH ) were obtained by reacting ortho-(butoxymethoxymethyl)phenylmagnesium bromide with derivatives of chloromethylphosphonic and chloromethylph osphinic acids, followed by intramolecular alkylation. X-Ray diffracti on was used to study the molecular and crystalline structure of one of these compounds (with X = OH).