L. Hellner et al., ION PHOTODESORPTION FROM HYDROGENATED SILICON (111) SURFACES, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 78(1-4), 1993, pp. 342-345
Electronic processes responsible for the breaking of Si-H bonds on hyd
rogenated Si (111) surfaces are investigated using a combination of ph
otoemission experiments and H+ ion photodesorption studies. H+ desorpt
ion is produced after Si(2p) core excitation between 100 and 112 eV. A
resonant process in the valence excitation range (20-30 eV) leads als
o to H+ desorption. These data confirm that electronic multi-excitatio
n rather than single electron excitation is involved in producing ion
desorption.