CHEMISTRY OF POLYFUNCTIONAL MOLECULES .11. FORMATION AND COMPLEX STABILIZATION OF A NEW CHAIN-LIKE PHOSPHAZENE ANION BY CO(II)-ASSISTED OXIDATIVE SCRAMBLING OF [N(PPH2)2]-

Authors
ELLERMANN J SUTTER J KNOCH FA MOLL M
Citation
J. Ellermann et al., CHEMISTRY OF POLYFUNCTIONAL MOLECULES .11. FORMATION AND COMPLEX STABILIZATION OF A NEW CHAIN-LIKE PHOSPHAZENE ANION BY CO(II)-ASSISTED OXIDATIVE SCRAMBLING OF [N(PPH2)2]-, Angewandte Chemie, International Edition in English, 32(5), 1993, pp. 700-701
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
5
Year of publication
1993
Pages
700 - 701
Database
ISI
SICI code
0570-0833(1993)32:5<700:COPM.F>2.0.ZU;2-V
Abstract
Cobalt(II) chloride acts as an oxidizing agent toward lithium bis(diph enylphosphino)amide! Surprisingly, in boiling toluene the two componen ts (molar ratio 1:2) form a phosphazene anion with scrambling of the a mide, which reacts further with cobalt(II) to give the spirocyclic met allaphosphazene 1.