CA3AUN - A CALCIUM AURIDE SUBNITRIDE

Authors
JAGER J STAHL D SCHMIDT PC KNIEP R
Citation
J. Jager et al., CA3AUN - A CALCIUM AURIDE SUBNITRIDE, Angewandte Chemie, International Edition in English, 32(5), 1993, pp. 709-710
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
5
Year of publication
1993
Pages
709 - 710
Database
ISI
SICI code
0570-0833(1993)32:5<709:C-ACAS>2.0.ZU;2-I
Abstract
A new auride with metallic character is a description of Ca3AuN, which crystallizes in the cubic Perowskite structure. The nitrogen atom is in the center of an octahedron of calcium atoms, and calcium and gold together form a cubic face-centered arrangement. The formula Ca32+Au-N 3- . 2e - is confirmed by the results of band structure calculations. Circle = Au, o = Ca, circle = N.