PI-HETEROATOM COMPLEXES .1. (ETA(1)-TPMN, ETA(5)-TPCR)-] (ETA(1)-TPCR, ETA(5)-TPMN) THIOPHENE (TP) CONVERSION DUE TO BIMETALLIC ACTIVATION - A NOVEL METAL-EXCHANGE REACTION

Authors
WALDBACH TA VANROOYEN PH LOTZ S
Citation
Ta. Waldbach et al., PI-HETEROATOM COMPLEXES .1. (ETA(1)-TPMN, ETA(5)-TPCR)-] (ETA(1)-TPCR, ETA(5)-TPMN) THIOPHENE (TP) CONVERSION DUE TO BIMETALLIC ACTIVATION - A NOVEL METAL-EXCHANGE REACTION, Angewandte Chemie, International Edition in English, 32(5), 1993, pp. 710-712
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
5
Year of publication
1993
Pages
710 - 712
Database
ISI
SICI code
0570-0833(1993)32:5<710:PC.(E(>2.0.ZU;2-V
Abstract
The irreversible formal exchange of the metal atoms in dinuclear compl exes has been observed for the first time. In polar solvents complex 1 rearranges to give the thermodynamically more stable complex 2.