THE SYNTHESIS AND ABINITIO STRUCTURE DETERMINATION OF ZN4O(BO3)2, A MICROPOROUS ZINCOBORATE CONSTRUCTED OF FUSED SUBUNITS OF 3-MEMBERED AND5-MEMBERED RINGS

Authors
HARRISON WTA GIER TE STUCKY GD
Citation
Wta. Harrison et al., THE SYNTHESIS AND ABINITIO STRUCTURE DETERMINATION OF ZN4O(BO3)2, A MICROPOROUS ZINCOBORATE CONSTRUCTED OF FUSED SUBUNITS OF 3-MEMBERED AND5-MEMBERED RINGS, Angewandte Chemie, International Edition in English, 32(5), 1993, pp. 724-726
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
5
Year of publication
1993
Pages
724 - 726
Database
ISI
SICI code
0570-0833(1993)32:5<724:TSAASD>2.0.ZU;2-K
Abstract
Vertex-sharing tetrahedral ZnO4 and triangular BO3 subunits form a thr ee-dimensional network of intersecting- channels in Zn4O(BO3)2, a new moleCular sieve not belonging to the aluminosilicates. The ab initio s tructure determination was possible with X-ray powder data: the pictur e on the right shows the view along [100].