ORGANO-GROUP-13 METAL-COMPLEXES OF THE D-BLOCK ELEMENTS .6. TRANSITION-METAL-SUBSTITUTED VOLATILE ALANES, GALLANES, AND INDANES - SYNTHESISAND STRUCTURE

Citation
Ra. Fischer et al., ORGANO-GROUP-13 METAL-COMPLEXES OF THE D-BLOCK ELEMENTS .6. TRANSITION-METAL-SUBSTITUTED VOLATILE ALANES, GALLANES, AND INDANES - SYNTHESISAND STRUCTURE, Angewandte Chemie, International Edition in English, 32(5), 1993, pp. 746-748
Citations number
14
Categorie Soggetti
Chemistry
ISSN journal
05700833
Volume
32
Issue
5
Year of publication
1993
Pages
746 - 748
Database
ISI
SICI code
0570-0833(1993)32:5<746:OMOTDE>2.0.ZU;2-D
Abstract
The instability and tendency to disproportionate of organometallic com pounds of Group 13 metal-d-metal complexes were countered by adjusting the donor acceptor properties of the metal centers. Now nothing prese nts the use of this class of compounds in layering processes or the de velopment of its chemistry. A large number of alanes, gallanes, and in danes related to 1 (M = Fe. L = Cp, n = 2) that are volatile without d ecomposition were prepared.