The structure of a-Si1-xCx:H thin films prepared from different mixtur
es of SiH4 and CH4 was studied by thermal desorption spectroscopy. The
influence of the gas phase composition and the thickness on the hydro
gen evolution spectra is presented and discussed. A third hydrogen evo
lution was observed in a-Si1-xCx films with higher carbon content. The
results show that the surface controlled desorption processes become
dominant when increasing the carbon content.