THERMAL TRANSFORMATIONS OF METAL-CARBONYL POLYACRYLONITRILES - IR ANDWAXS STUDY

Authors
LOGINOVA TP BRONSHTEIN LM MIRZOEVA ES EZERNITSKAYA MG LOKSHIN BV GENIN YV VALETSKII PM
Citation
Tp. Loginova et al., THERMAL TRANSFORMATIONS OF METAL-CARBONYL POLYACRYLONITRILES - IR ANDWAXS STUDY, Vysokomolekularnye soedinenia. Seria A, 35(1), 1993, pp. 10000028-10000032
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
35
Issue
1
Year of publication
1993
Pages
10000028 - 10000032
Database
ISI
SICI code
0507-5475(1993)35:1<10000028:TTOMP->2.0.ZU;2-0
Abstract
Thermal transformations in metal-containing PANs based on VIB group me tal hexacarbonyls were studied by IR spectroscopy and the data were co mpared with those for the initial (metal-free) polymer. The behavior o f nitrile groups of PAN was found to depend on thermolysis conditions and the type of metal-polymer complex. Thermolysis-induced changes in the structure of the metal-containing and the initial PAN samples were studied by WAXS techniques.