AN INVESTIGATION OF THE INTERACTION BETWE EN EPOXY AND ESTER

Citation
Sa. Kosikhina et al., AN INVESTIGATION OF THE INTERACTION BETWE EN EPOXY AND ESTER, Vysokomolekularnye soedinenia. Seria A, 35(1), 1993, pp. 20000022-20000025
Citations number
13
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
35
Issue
1
Year of publication
1993
Pages
20000022 - 20000025
Database
ISI
SICI code
0507-5475(1993)35:1<20000022:AIOTIB>2.0.ZU;2-5
Abstract
Interactions between epoxy and ester groups in a model system were stu died using a number of methods, including isothermal calorimetry, gel- permeation chromatography, and IR spectroscopy. A mechanism is propose d describing the insertion of epoxy groups into the ester ones. The re action is shown to result in the generation of oligomeric products via the formation of cyclic orthoester as an intermediate product.