FLOW-INJECTION CHEMILUMINESCENCE METHOD FOR THE SELECTIVE DETERMINATION OF CHROMIUM(III)

Flow injection (FI) has been applied to the determination of Cr(III) i n water and food samples. The method is based on measurement of the li ght emitted from the Cr(III)-catalysed oxidation of luminol by H2O2. T he apparatus consists of an FI system with a flow cell suitable for ch emiluminescence detection. The flow cell, situated near the photodetec tor, is a coiled tube made from transparent poly(tetrafluoroethylene. The typical signal is a narrow peak, the height of which is proportion al to the light emitted and, therefore, to the concentration of Cr(III ). The detection limit is 0.01 ppb and the linear range extends up to 6 ppb. The concentrations of the reagents, the pH and the flow rates w ere optimized. Interferences by several metal ions were examined, and the system was shown to possess a high selectivity. The method was suc cessfully applied to the determination of Cr(III) in water and food sa mples.