SYNTHESIS OF OLIGOMERS WITH TRIPLE SIDE-C HAIN BONDS

Citation
Lv. Morozova et al., SYNTHESIS OF OLIGOMERS WITH TRIPLE SIDE-C HAIN BONDS, Vysokomolekularnye soedinenia. Seria A, 35(5), 1993, pp. 20000272-20000274
Citations number
8
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
35
Issue
5
Year of publication
1993
Pages
20000272 - 20000274
Database
ISI
SICI code
0507-5475(1993)35:5<20000272:SOOWTS>2.0.ZU;2-H
Abstract
Ethylene glycol vinylpropargyl diether was synthesized via the reactio n of ethylene glycol vinyl ether with propargyl chloride under conditi ons of interfacial catalysis. Selective polymerization of the monomer in the presence of iron chloride and boron trifluoride etherate allowe d the obtaining of new reactive oligomers with acetylene groups in the side chain. The possibility of modification of these oligomers in hyd rogenation and aminomethylation reactions was demonstrated.