Vg. Danilov et Vi. Shilkin, INCORPORATION MECHANISM FOR DOPING OF METAL-IONS INTO A PASSIVATING FILM AT THE LITHIUM THIONYL CHLORIDE INTERFACE, Journal of power sources, 45(1), 1993, pp. 7-13
Effects of iron and titanium ions on corrosion processes of lithium in
thionyl chloride electrolytes have been studied. Laws for the growth
of the passivating film on the type and concentration of doped ions ha
ve been established, and equations for these are suggested. A stepwise
mechanism of dopant incorporation into passivating film structure is
presented.