Epitaxial body-centered cubic Mo and Cr films have been grown on the (
111) surface of alpha-Fe films on Si(111) at 300 and 575 K by electron
beam evaporation in ultrahigh vacuum. X-ray diffraction and transmiss
ion electron microscopy show that the Mo films are oriented with the (
111) plane parallel to the alpha-Fe(111) plane and with the Mo[110BAR]
direction parallel to the Fe[110BAR] direction in the plane of the su
bstrate. The same orientation relationship holds for the Cr films epit
axially grown on alpha-Fe(111) surfaces. Epitaxial Fe(111)/Mo(111)/Fe(
111) and Fe(111)/Cr(111)/Fe(111) films have also been grown on Si(111)
. This work provides new examples of low temperature epitaxy which can
occur at a substrate temperature as low as 0.1 times the melting temp
erature of the deposited materials.