GeSe2 can exist in both amorphous and crystalline phases. Although mos
t semiconductor devices are constructed from crystalline materials, th
e use of amorphous materials in devices has high potential. The study
of GeSe2 is especially interesting since it has been established that
an amorphous-to-crystalline transition can be induced by laser irradia
tion. In order to better understand this phenomenon, it is necessary t
o study the microstructure of GeSe2 glass. Therefore, transmission ele
ctron microscopy studies were undertaken to investigate the degree of
crystallinity of GeSe2 glass. It was found that small microcrystallite
s with diameters in the range of 100-300 angstrom were embedded in a g
lass matrix. These microcrystallites formed larger clusters in some ar
eas.