A thermodynamic analysis by calorimetric experiments in a system with
changing pressure is presented. A general equation is derived for use
in calculating the rate of heat loss from measured mass flow rate. The
results show that the largest contribution from pressure variation is
the sensible heat of liquid helium in a Dewar. A dimensionless parame
ter that was identified provides an indication of the importance of pr
essure variation relative to the latent heat of vaporization during an
experiment. This dimensionless parameter is a function of system pres
sure (and the thermodynamic properties of helium), rate of change of s
ystem pressure, liquid helium inventory in the Dewar and measured mass
flow rate. In the special case when the effect of pressure variation
is small compared to the latent heat of vaporization, the heat loss ra
te is the product of the measured mass flow rate and the latent heat o
f vaporization, multiplied by a correction factor that is a function o
f the ratio of vapour density to liquid density. This correction facto
r is significant for helium at pressures near or above 1 atm and shoul
d always be included in the calculation.