C. Braux et al., LE-CHATELET GOLD-BEARING ARSENOPYRITE DEPOSIT, MASSIF-CENTRAL, FRANCE- MINERALOGY AND GEOCHEMISTRY APPLIED TO PROSPECTING, Applied geochemistry, 8(4), 1993, pp. 339-356
The abundant data available on the geochemistry and mineralogy of the
Hercynian gold deposit of Le Chatelet (Massif Central, France) formed
the basis for an analysis of the complex signature of a gold deposit a
nd its hydrothermal alteration haloes. This study describes the deposi
t and its environment at various scales. The sulfide paragenesis of th
e Le Chatelet deposit resulted from several stages, one of which was a
n event responsible for the deposition of Au-bearing arsenopyrite quar
tz veins; the Au is contained within the arsenopyrite lattice. Hydroth
ermal activity associated with these veins produced two superimposed a
lteration haloes: an outer halo of kaolinite + tosudite + siderite alt
eration that developed at the expense of the plagioclase minerals, and
an inner halo of illite +/- siderite alteration that affected all the
minerals. The hydrothermal alteration was followed by silicification
of the wall rocks and then deposition of the Au-bearing arsenopyrite.
The hydrothermal alteration related to the event also generated geoche
mical signatures such as Li, B, LREE, As, Sb, Au and W anomalies. Mine
ralogical studies and geochemical analyses of the hydrothermal facies
show that: (1) the anomalous Li is trapped mainly in the tosudite latt
ice and to a lesser degree in the illite lattice; and (2) the B is pro
bably located in tosudite and illite lattices. Arsenic, Sb and Au are
contained in the arsenopyrite lattice. During weathering, the lithoche
mical signatures (determined by the analytical techniques used in this
study) lose some of their specific characteristics, depending on the
original concentrations. At deposit scale (0.25-1.0 km 2) , B and Li i
n the soil profiles indicate zones of hydrothermal alteration, whereas
As and Au indicate zones of mineralization. At a regional scale, the
association of Au, As, Li and B in stream sediments is characteristic
of this type of mineralization. Therefore, in the hydrothermal setting
described at Le Chatelet, Au, As, Li and B appear, at all scales, to
be dependable pathfinders for Au-bearing hydrothermal systems of possi
ble, economic interest.