AN EPR AND MOLECULAR MECHANICS STUDY OF RADICAL ADDUCTS OF PHOSPHONYLRADICALS WITH 2-HYDROPERFLUORO-4-METHYL-2-PENTENE AND 4,4-DIMETHYL-2-PENTENE

Authors
TUMANSKII BL SNEGIREV VF MAKAROV KN LANTSEVA LT SOLODOVNIKOV SP BUBNOV NN TIMOFEEVA TV STRUCHKOV YT
Citation
Bl. Tumanskii et al., AN EPR AND MOLECULAR MECHANICS STUDY OF RADICAL ADDUCTS OF PHOSPHONYLRADICALS WITH 2-HYDROPERFLUORO-4-METHYL-2-PENTENE AND 4,4-DIMETHYL-2-PENTENE, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(11), 1992, pp. 2008-2011
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
11
Year of publication
1992
Part
1
Pages
2008 - 2011
Database
ISI
SICI code
1063-5211(1992)41:11<2008:AEAMMS>2.0.ZU;2-E
Abstract
EPR spectra of radical adducts of phosphonyl radicals with 2-hydroperf luoro-4-methyl- and 4,4-dimethyl-2-pentene have been studied. The mole cular mechanics method has been used to determine the preferred confor mation of the (CF3)2CF-CF-HCF3P(O)(OMe)2 radical. The eclipsed conform ation of the C-P bond and 2p(z)-orbital of an unpaired electron is sta bilized due to steric factor and hyperconjugation.