A new type of superlattice based on a periodic array of twinned stacki
ng faults is proposed. Such superlattices based on Si and Ge are predi
cted to be characterised by zero miniband energy gaps, evanescent stat
e derived Bloch minibands and minibands with anomalous dispersion. The
y can be direct band gap materials and offer the significant benefits
of simple chemistry, lack of stress and a favoured technological envir
onment.