Yj. Lee et al., SYNTHESIS OF Y-BA-CU-O SUPERCONDUCTORS USING ORGANOMETALLIC PRECURSORS, Materials science & engineering. B, Solid-state materials for advanced technology, 19(3), 1993, pp. 257-260
Organometallic precursors from naphthenic acid and metal nitrates were
used for the synthesis of YBa2Cu3O(7-x) (so called YBCO or 123) super
conducting compounds. The characteristics of metal naphthenates as org
anometallic precursors were investigated by IR spectra and viscosity m
easurements. 123 superconducting compound obtained from 123 naphthenat
e showed a T(c) of 90-degrees-K and a rather dense and elongated micro
structure. Four probe resistance measurements and carbon content deter
minations were carried out to characterize superconducting properties
of the samples obtained in this study.