THE REDOX BEHAVIOR OF FERROCENE DERIVATIVES .5. 6,5-LAMBDA(5)-DITHIATRIAZAPHOSPHORINE-1,3-DIOXIDE)

Authors
ZANELLO P OPROMOLLA G GIORGI G VANDEGRAMPEL JC SCHOO HFM
Citation
P. Zanello et al., THE REDOX BEHAVIOR OF FERROCENE DERIVATIVES .5. 6,5-LAMBDA(5)-DITHIATRIAZAPHOSPHORINE-1,3-DIOXIDE), Polyhedron, 12(11), 1993, pp. 1329-1333
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
11
Year of publication
1993
Pages
1329 - 1333
Database
ISI
SICI code
0277-5387(1993)12:11<1329:TRBOFD>2.0.ZU;2-R
Abstract
Preparation of the title compound (1) is reported together with its de tailed mass spectrometric investigations, which revealed the high stab ility of the molecular ion under electron impact and allow its fragmen tation pathways to be rationalized. In dichloroethane solution the one -electron oxidation of 1 occurs at the highest potential value so far known for ferrocene molecules (E-degrees' = + 1.19 V, vs S.C.E.).