AN N-15 NMR SPECTROSCOPIC STUDY OF SOME RHODIUM COMPLEXES OF 3,5-DICARBOMETHOXY-4-PHENYLPYRIDINE-N-15

Authors
CARLTON L DESOUSA G
Citation
L. Carlton et G. Desousa, AN N-15 NMR SPECTROSCOPIC STUDY OF SOME RHODIUM COMPLEXES OF 3,5-DICARBOMETHOXY-4-PHENYLPYRIDINE-N-15, Polyhedron, 12(11), 1993, pp. 1377-1382
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
11
Year of publication
1993
Pages
1377 - 1382
Database
ISI
SICI code
0277-5387(1993)12:11<1377:ANNSSO>2.0.ZU;2-C
Abstract
N-15 NMR data are reported for the complexes [cis-RhX(PPh3)2(dcpp-N-15 )], [Rh(H)2X(PPh3)2(dCPP-N-15)] (X = Cl, SC6F5; dcpp-N-15 = 3,5-dicarb omethoxy-4-phenylpyridine-N-15), [RhCl(PPh3)(L)(dcpp-N-15)] (L = C2H4, CO) and [Rh(H)(C2Ph)(X) (PPh3)2(dcpp-N-15)] (X = Cl, OCN, N3, C2Ph), prepared in situ from [RhX(PPh3)3], [Rh2Cl2(C2H4)4] and [Rh2(SC6F5)2(P Ph3)4].