OXIDATION REACTIONS BY THE COORDINATED NITROSYL GROUP

Authors
DEB AK GOSWAMI S
Citation
Ak. Deb et S. Goswami, OXIDATION REACTIONS BY THE COORDINATED NITROSYL GROUP, Polyhedron, 12(11), 1993, pp. 1419-1421
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
11
Year of publication
1993
Pages
1419 - 1421
Database
ISI
SICI code
0277-5387(1993)12:11<1419:ORBTCN>2.0.ZU;2-T
Abstract
The oxidation reaction by the coordinated nitrosyl group in [Ru(NO)(NO 2)(M-tap)2](ClO4)2 (1) (M-tap = m-tolylazopyridine) is described. Comp lex 1 brings about the oxidative coupling of N,N-dimethylaniline (DMA) to tetramethylbenzidine (TMB) and the oxidation of RuCl2(bpy) 2 (bpy = 2,2'-bipyridine) to [RUCI2(bpy)2]+. These redox reactions have been studied voltametrically and the results have been analysed in terms of the electrophilicity of the coordinated NO' in 1.