SYNTHESIS AND CHARACTERIZATION OF TETRAPHENYLARSONIUM AMIDE, OXIME AND CARBOXYLATE DERIVATIVES

Authors
SINGHAL K RAJ P
Citation
K. Singhal et P. Raj, SYNTHESIS AND CHARACTERIZATION OF TETRAPHENYLARSONIUM AMIDE, OXIME AND CARBOXYLATE DERIVATIVES, Synthesis and reactivity in inorganic and metal-organic chemistry, 23(6), 1993, pp. 1011-1020
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
23
Issue
6
Year of publication
1993
Pages
1011 - 1020
Database
ISI
SICI code
0094-5714(1993)23:6<1011:SACOTA>2.0.ZU;2-A
Abstract
New representative pentacoordinate tetraphenylarsoniumamide oxime and carboxylate derivatives of type Ph4AsL, where L = NR2 = -NCO(CH2)2CO, -NCOC6H4CO, -NNNC6H4, NCOCOC6H4; OOCR(I) (R(I) = -C6H4NO2-m, C6H4Cl-o) and and ONCR(II)R(II I) (R(II), R(I II) = Me, Ph; Ph, Ph, and (CH2)5) have been isolated and characterized by elemental analyses, molar con ductance, molecular weight determination, infrared and (I)H NMR spectr al data. A tentative trigonal bipyramidal structure has been proposed for these derivatives.