COMMENTS ON DIFFERENT SYNTHETIC METHODS FOR THE PREPARATION OF DIAMINE AND BIS(AMINE) ORGANODICARBOXYLATOPLATINUM(II) COMPLEXES

Authors
PASINI A CALDIROLA C SPINELLI S VALSECCHI M
Citation
A. Pasini et al., COMMENTS ON DIFFERENT SYNTHETIC METHODS FOR THE PREPARATION OF DIAMINE AND BIS(AMINE) ORGANODICARBOXYLATOPLATINUM(II) COMPLEXES, Synthesis and reactivity in inorganic and metal-organic chemistry, 23(6), 1993, pp. 1021-1060
Citations number
79
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
23
Issue
6
Year of publication
1993
Pages
1021 - 1060
Database
ISI
SICI code
0094-5714(1993)23:6<1021:CODSMF>2.0.ZU;2-Y
Abstract
Various synthetic routes to [PtA2(dic)] (1, A = NH3, amine, or 1/2 dia mine; dic, chelated organodicarboxylate) are reviewed and discussed in the light of the literature and our experience. Emphasis is given to yields and purity of the intermediates and the products. A simple puri fication procedure is described. The mechanism of the reaction between bis(amine)dihydroxoplatinum(II) complexes and dicarboxylic acids has been investigated by Pt-195 n.m.r. Representative preparations of some selected compounds 1, including some new highly water soluble derivat ives, are described in the Experimental section.