Specific heats of a range of coals, cokes and ashes have been measured
from 300 to 600 K (coals, cokes) or 1000 K (ashes) using differential
scanning calorimetry. There is a rapid increase of specific heat with
the content of volatile matter in the region 0-10 wt% followed by onl
y mild increases at higher concentrations. A general equation is given
expressing the heat capacity of a daf coal in terms of proximate comp
osition and temperature. It provides a simple and accurate method of a
ssessing enthalpy changes up to 600 K-the onset of volatilization for
many bituminous coals.