Atomically clean polycrystalline gold was bombarded by slow cluster io
ns (N2)n+ (n less-than-or-equal-to 100), Ne(n)+ (n less-than-or-equal-
to 100) and C60q (q less-than-ro-equal-to + 5; - 1) of kinetic energie
s from the apparent electron emission thresholds up to 6 kV times the
cluster charge (qe). The resulting electron emission yields have been
derived from the corresponding electron emission statistics. Grossly d
ifferent electron yields were found for different cluster species of t
he same velocity and similar mass, which is attributed to different pa
rtitioning of the initial cluster kinetic energy among a) inelastic bi
nary collision processes involving cluster constituents and surface at
oms, and b) vibrational excitation (when possible). For (N2)n cluster
ions clear evidence of a non-linear behaviour (i.e. increasing electro
n emission per cluster constituent with increasing cluster size) was o
bserved.