In briefly annealed silicon samples implanted with hydrogen and deuter
ium an electron paramagnetic resonance spectrum is detected. It is ide
ntified as arising from a hydrogen molecule oriented in the [111] crys
tallographic direction and located most probably at an interstitial si
te. Such a result is consistent with recent theoretical calculations p
redicting such an orientation to be of lowest energy. In addition, evi
dence is obtained indicating that the hydrogen molecule forms a part o
f a more elaborate hydrogen cluster.