THE [NI(CO)4]-PROMOTED CARBONYLATIVE CYCLOADDITION OF ALKYNES AND ALLYL HALIDES FOR THE SYNTHESIS OF 2-CYCLOPENTENONE DERIVATIVES

Authors
LLEBARIA A MORETO JM
Citation
A. Llebaria et Jm. Moreto, THE [NI(CO)4]-PROMOTED CARBONYLATIVE CYCLOADDITION OF ALKYNES AND ALLYL HALIDES FOR THE SYNTHESIS OF 2-CYCLOPENTENONE DERIVATIVES, Journal of organometallic chemistry, 451(1-2), 1993, pp. 1-13
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
451
Issue
1-2
Year of publication
1993
Pages
1 - 13
Database
ISI
SICI code
0022-328X(1993)451:1-2<1:T[CCOA>2.0.ZU;2-8
Abstract
The [Ni(CO)4]-mediated carbonylative cycloaddition of alkynes and ally l halides first reported by Chiusoli, has been reviewed, extended and optimized for application to cyclopentenone synthesis. An insight into the reaction mechanism is also given to explain the results obtained, in particular the regio- and stereo-chemistry of the process.