A NEW TRIALKOXYSILYLATION REACTION, THE CROSS-COUPLING OF (TRI-ISOPROPYLOXYSILYL)METHYL GRIGNARD-REAGENT WITH ORGANIC HALIDES

Citation
Dj. Brondani et al., A NEW TRIALKOXYSILYLATION REACTION, THE CROSS-COUPLING OF (TRI-ISOPROPYLOXYSILYL)METHYL GRIGNARD-REAGENT WITH ORGANIC HALIDES, Journal of organometallic chemistry, 451(1-2), 1993, pp. 30000001-30000003
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
451
Issue
1-2
Year of publication
1993
Pages
30000001 - 30000003
Database
ISI
SICI code
0022-328X(1993)451:1-2<30000001:ANTRTC>2.0.ZU;2-H
Abstract
The reaction of tri-isopropyloxy(chloromethyl)silane with magnesium le d to stable THF solutions of the Grignard reagent. The latter underwen t coupling reactions with organic bromides to give high yields of tria lkoxysilylated compounds.