CARBONYLATION OF ORGANIC ALLYL MOIETIES .4. UNEXPECTED FORMATION OF CYCLIC ESTERS FROM THE CARBONYLATION OF ALKOXYOCTADIENES IN THE PRESENCE OF RHODIUM CATALYSTS

Citation
Mm. Barretorosa et al., CARBONYLATION OF ORGANIC ALLYL MOIETIES .4. UNEXPECTED FORMATION OF CYCLIC ESTERS FROM THE CARBONYLATION OF ALKOXYOCTADIENES IN THE PRESENCE OF RHODIUM CATALYSTS, Journal of organometallic chemistry, 451(1-2), 1993, pp. 30000022-30000024
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
451
Issue
1-2
Year of publication
1993
Pages
30000022 - 30000024
Database
ISI
SICI code
0022-328X(1993)451:1-2<30000022:COOAM.>2.0.ZU;2-X
Abstract
Mixtures of 1-methoxy- and 3-methoxy-octadienes are readily converted into epimeric 2-vinylcyclopentylacetates, under moderate pressures of CO in the presence of rhodium chloride and hydrochloric acid.