CARBONYLATION OF ORGANIC ALLYL MOIETIES .4. UNEXPECTED FORMATION OF CYCLIC ESTERS FROM THE CARBONYLATION OF ALKOXYOCTADIENES IN THE PRESENCE OF RHODIUM CATALYSTS
Mm. Barretorosa et al., CARBONYLATION OF ORGANIC ALLYL MOIETIES .4. UNEXPECTED FORMATION OF CYCLIC ESTERS FROM THE CARBONYLATION OF ALKOXYOCTADIENES IN THE PRESENCE OF RHODIUM CATALYSTS, Journal of organometallic chemistry, 451(1-2), 1993, pp. 30000022-30000024
Mixtures of 1-methoxy- and 3-methoxy-octadienes are readily converted
into epimeric 2-vinylcyclopentylacetates, under moderate pressures of
CO in the presence of rhodium chloride and hydrochloric acid.