BIS(PHOSPHINE)GOLD(I) DERIVATIVES WITH 7,7',8,8'-TETRACYANOQUINODIMETHANE X-RAY STRUCTURE OF [AU(PPH3)2]TCNQ

Authors
ALONSO PJ CERRADA E GARIN J GIMENO MC LAGUNA A LAGUNA M JONES PG
Citation
Pj. Alonso et al., BIS(PHOSPHINE)GOLD(I) DERIVATIVES WITH 7,7',8,8'-TETRACYANOQUINODIMETHANE X-RAY STRUCTURE OF [AU(PPH3)2]TCNQ, Synthetic metals, 56(1), 1993, pp. 1772-1776
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
56
Issue
1
Year of publication
1993
Pages
1772 - 1776
Database
ISI
SICI code
0379-6779(1993)56:1<1772:BDW7>2.0.ZU;2-O
Abstract
The complexes [Au(PR3)2]ClO4 (PR3 = PPh3, PPh2Me, P(p-MeC6H4)3 or P(p- MeOC6H4)3) react with LiTCNQ to give Au(PR3)2TCNQ. The same results ar c obtained if free TCNQ is present in the reaction mixture. The struct ure of [Au(PPh3)2TCNQ] has been established by single-crystal X-ray di ffraction studies and shows a short Au ... N contact of 3.21 angstrom.