SYNTHESIS AND CHARACTERIZATION OF THE 1ST PALLADIUM NONINTEGER OXIDATION-STATE COMPLEX OF THE DSIT LIGAND

Authors
FAULMANN C LEGROS JP CASSOUX P CORNELISSEN JC HAASNOOT JG REEDIJK J
Citation
C. Faulmann et al., SYNTHESIS AND CHARACTERIZATION OF THE 1ST PALLADIUM NONINTEGER OXIDATION-STATE COMPLEX OF THE DSIT LIGAND, Synthetic metals, 56(1), 1993, pp. 2063-2068
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
56
Issue
1
Year of publication
1993
Pages
2063 - 2068
Database
ISI
SICI code
0379-6779(1993)56:1<2063:SACOT1>2.0.ZU;2-X
Abstract
The synthesis and crystal structure of the first non-integer oxydation state complex of the dsit ligand, [(CH3)4N][Pd(dsit)2]2, are reported . This compound was prepared by electrochemical oxidation of the dival ent [(CH3)4N]2[Pd(dsit)2] comPlex, and is isostructural with the molec ular superconductor beta-[(CH3)4N][Pd(dmit)2]2.