2,3,6,7-TETRAKIS(METHYLTHIO)NAPHTHALENE - SYNTHESIS AND CATION-RADICAL SALT

Authors
HELLBERG J SODERHOLM S NORELAND J BIETSCH W VONSCHUTZ JU
Citation
J. Hellberg et al., 2,3,6,7-TETRAKIS(METHYLTHIO)NAPHTHALENE - SYNTHESIS AND CATION-RADICAL SALT, Synthetic metals, 56(1), 1993, pp. 2102-2107
Citations number
20
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
56
Issue
1
Year of publication
1993
Pages
2102 - 2107
Database
ISI
SICI code
0379-6779(1993)56:1<2102:2-SAC>2.0.ZU;2-A
Abstract
The three step synthesis of 2,3,6,7-Tetrakis(methylthio)naphthalene (T MTN) 1 is described. The title donor gives a 1: 1 salt with hexafluoma rsenate anion. The crystal structure consists of a dimerized donor sta ck, with alternate stacking. The conductivity is activated, room tempe rature conductivity; almost-equal-to 10(-3).10-4 Scm-1. The susceptibi lity is quite low, chi(300K)= 7-10(-7) emu/mol, and the ESR linewidth is DELTAB(pp)(300K)almost-equal-to 5 G. [GRAPHICS]