CATION-RADICAL SALTS OF THE TETRATHIAFULVALENE SERIES - FAST MIXED-VALENCE DETECTION BY THIN-LAYER CYCLIC VOLTAMMETRY

Authors
CARLIER R TALLEC A FRERE P SALLE M JUBAULT M GORGUES A COUSSEAU J
Citation
R. Carlier et al., CATION-RADICAL SALTS OF THE TETRATHIAFULVALENE SERIES - FAST MIXED-VALENCE DETECTION BY THIN-LAYER CYCLIC VOLTAMMETRY, Synthetic metals, 56(1), 1993, pp. 2359-2363
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
56
Issue
1
Year of publication
1993
Pages
2359 - 2363
Database
ISI
SICI code
0379-6779(1993)56:1<2359:CSOTTS>2.0.ZU;2-T
Abstract
The detection and evaluation of mixed valence states in cation radical salts (CRS) of the tetrathiafulvalene (TTF) series are readily achiev ed by using thin layer cyclic voltammetry (TLCV) with an internal coul ometric reference. The method has proved to be valid for the mixed val ence determination of the following typical well known CRS : TTFBr0.75 , TMTTF(PF6)0.5, TMTSF(PF6)0.5, BEDTTTF(PF6)0.5, BEDTTTF(BF4)0.5.