ASSIGNMENT OF FUNDAMENTAL VIBRATIONS AND ESTIMATION OF ELECTRON-MOLECULAR VIBRATION COUPLING-CONSTANTS FOR BIS(ETHYLENEDIOXY)TETRATHIAFULVALENE (BEDO)

Authors
POKHODNIA KI KOZLOV ME ONISCHENKO VG SCHWEITZER D MOLDENHAUER J ZAMBONI R
Citation
Ki. Pokhodnia et al., ASSIGNMENT OF FUNDAMENTAL VIBRATIONS AND ESTIMATION OF ELECTRON-MOLECULAR VIBRATION COUPLING-CONSTANTS FOR BIS(ETHYLENEDIOXY)TETRATHIAFULVALENE (BEDO), Synthetic metals, 56(1), 1993, pp. 2364-2371
Citations number
12
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
56
Issue
1
Year of publication
1993
Pages
2364 - 2371
Database
ISI
SICI code
0379-6779(1993)56:1<2364:AOFVAE>2.0.ZU;2-Z
Abstract
The i.r. absorption and Raman spectra of BEDO are investigated. All fu ndamental vibrations are assigned using correlations between the obtai ned data and those for a well-known compound BEDT-TTF (ET). Comparativ e normal coordinate analysis has been done. The results are used for c alculation of electron-intramolecular vibration coupling constants of BEDO based superconducting charge-transfer complexes. Comparison of th ese values with the constants obtained earlier for ET shows that BEDO is a perspective donor for searching new superconductors on its basis.