Y. Tazuke et T. Takeyama, MAGNETIC-PROPERTIES OF 3D TRANSITION ELEMENT INTERCALATED COMPOUNDS MSTISE(2), Journal of the Physical Society of Japan, 66(3), 1997, pp. 827-830
Polycrystalline samples of M(x)TiSe(2) with M=V, Cr, Mn, Fe, Co, Ni an
d Cu were prepared. All the compounds showed paramagnetic behavior at
4.2 K less than or equal to T less than or equal to 300 K. Effective p
aramagnetic moment mu(eff) of all the M-atoms are much smaller than io
nic values, suggesting that the M-states are strongly hybridized with
the TiSe2-band. Cr Mn, Fe and Co may be in the high-spin states. The m
u(eff)-data are compared with those of TyTiS2 with T=V: Mn, Fe, Co. Ni
and Cu in our previous studies and with the band calculation results
of Motizuki et al., and discussions are done about the electronic stat
es of T- and M-atoms. It is suggested that the S-3p states are hardly
hybridized and the Se-Sp states are slightly hybridized with a Ti-3d e
psilon non-bonding band.