SURFACE SPIN CANTING IN BAFE12O19 FINE PARTICLES

Several samples of BaFe12O19 were prepared by the 'liquid mix' techniq ue. The dependence of both particle size and macroscopic magnetic para meters on the synthesis procedure was studied by means of X-ray powder diffraction and high-field magnetization measurements. It is shown th at particle size increases and magnetic parameters approach the intrin sic ones as the synthesis temperature and time rise. Besides, the non- collinearity of the surface spins tends to reduce the saturation magne tization and the degree of reduction is strongly dependent on particle size through the surface-to-volume ratio. Some approximations have be en considered to check this effect: we have assumed that the spin cant ing takes place in the outer region near the surface, while in the inn er region the magnetic structure is that of a bulk and the magnetic mo ments remain collinear to the easy magnetization axis (shell model). T he possibility of surface spin canting in the basal and side planes is also discussed. Some other hypotheses concerning the evolution of the spin canting angle inside the particle are tested. The results obtain ed suggest that the width of the surface region where spins are non-co llinear depends on particle size and it may range from a few to some t ens of Angstroms.