Adding waxy maize starch phosphate monoesters to milk caused a decreas
e in heat stability. Crosslinked waxy maize starch phosphate monoester
s had a smaller detrimental effect than native waxy maize or starch mo
nophosphates prepared from non-crosslinked waxy maize. The results sug
gest that starch phosphate monoesters exert a destabilising effect rel
ated to the hydrated molecular volume of the starch components and a s
tabilising effect related to the presence of phosphate groups. There i
s a threshold phosphorylation level above which the phosphate groups c
ounteract the destabilising effect of the hydrated molecular volume.