STRUCTURAL STUDIES ON 3-ACETYL-1,5-DIARYL AND 3-CYANO-1,5-DIARYL FORMAZAN CHELATES WITH CERIUM(III), THORIUM(IV) AND URANIUM(VI)

Authors
SHERIF OE ISSA YM HASSOUNA MEM ABASS SM
Citation
Oe. Sherif et al., STRUCTURAL STUDIES ON 3-ACETYL-1,5-DIARYL AND 3-CYANO-1,5-DIARYL FORMAZAN CHELATES WITH CERIUM(III), THORIUM(IV) AND URANIUM(VI), Monatshefte fuer Chemie, 124(6-7), 1993, pp. 627-635
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Monatshefte fuer Chemie → ACNP
ISSN journal
00269247
Volume
124
Issue
6-7
Year of publication
1993
Pages
627 - 635
Database
ISI
SICI code
0026-9247(1993)124:6-7<627:SSO3A3>2.0.ZU;2-S
Abstract
Solid complexes of 3-acetyl- 1,5-diaryl and 3-cyano- 1,5-diaryl formaz ans were prepared and characterized by elemental analysis, IR, NMR, TG A and DTA analyses. Based on these studies, the suggested general form ula for the complexes is [M(HL)m(OH-)n or (NO3- or Cl-)x.(H2O)y or (C2 H5OH or DMSO)z, where HL = formazan M = Ce3+, Th4+, and UO22+, m = 1-2 , n = 0-3, x = 0-3, y = 0-4 and z = 0-3. The metal ions are expected t o have coordination numbers 6-8.