THE INVENTION OF RADICAL REACTIONS .31. DIPHENYLSILANE - A REAGENT FOR DEOXYGENATION OF ALCOHOLS VIA THEIR THIOCARBONYL DERIVATIVES, DEAMINATION VIA ISONITRILES, AND DEHALOGENATION OF BROMO-COMPOUNDS AND IODO-COMPOUNDS BY RADICAL-CHAIN CHEMISTRY

Authors
BARTON DHR JANG DO JASZBERENYI JC
Citation
Dhr. Barton et al., THE INVENTION OF RADICAL REACTIONS .31. DIPHENYLSILANE - A REAGENT FOR DEOXYGENATION OF ALCOHOLS VIA THEIR THIOCARBONYL DERIVATIVES, DEAMINATION VIA ISONITRILES, AND DEHALOGENATION OF BROMO-COMPOUNDS AND IODO-COMPOUNDS BY RADICAL-CHAIN CHEMISTRY, Tetrahedron, 49(33), 1993, pp. 7193-7214
Citations number
70
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
49
Issue
33
Year of publication
1993
Pages
7193 - 7214
Database
ISI
SICI code
0040-4020(1993)49:33<7193:TIORR.>2.0.ZU;2-V
Abstract
Various thionocarbonates and xanthates of alcohols and bis-xanthates o f vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with dipheny lphenylsilane in good yield.