OSCILLATIONS OF REACTIVITY IN THE [2-CYCLOADDITION OF METHYL ACRYLATETO FURAN(4])

Authors
ZHULIN VM KORESHKOV YD BOGDANOV VS KELTSEVA MV
Citation
Vm. Zhulin et al., OSCILLATIONS OF REACTIVITY IN THE [2-CYCLOADDITION OF METHYL ACRYLATETO FURAN(4]), Russian chemical bulletin, 45(10), 1996, pp. 2321-2326
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
10
Year of publication
1996
Pages
2321 - 2326
Database
ISI
SICI code
1066-5285(1996)45:10<2321:OORIT[>2.0.ZU;2-U
Abstract
The kinetics of [2+4]-cycloaddition of methyl acrylate to furan (Diels -Alder reaction) were studied at 70 degrees C and 907 MPa, i.e., under conditions where the solvent (benzene) exists in the solid state. It was found that the reactivity exhibits oscillations with astronomic ti me and that its averaging leads to reaction rate constants, which are close to those expected from the calculations, carried out using the k nown reaction and activation volume effects and the reactivity at a pr essure close to the atmospheric pressure.