THE REACTION OF ETHYL 2,6-DIMETHYL-1,4-DIHYDROPYRIDINE-3,5-DICARBOXYLATE WITH FULLERENE C-60

Authors
GOLDSHLEGER NF ASTAKHOVA AS LOBACH AS BOIKO GN DENISOV NN NADTOCHENKO VA ROSHCHUPKINA OS SHULGA YM
Citation
Nf. Goldshleger et al., THE REACTION OF ETHYL 2,6-DIMETHYL-1,4-DIHYDROPYRIDINE-3,5-DICARBOXYLATE WITH FULLERENE C-60, Russian chemical bulletin, 45(10), 1996, pp. 2402-2404
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
10
Year of publication
1996
Pages
2402 - 2404
Database
ISI
SICI code
1066-5285(1996)45:10<2402:TROE2>2.0.ZU;2-5
Abstract
Heating (100 degrees C, toluene) or photolysis (Nd3+ : YAG laser, lamb da = 532 nm, benzonitrile) of a mixture of ethyl 2,6-dimethyl-1,4-dihy dropyridine-3,5-dicarboxylate (Hantsch ester) (1) and fullerene C-60 u nder anaerobic conditions results in the formation of fullerene hydrog enation products and ethyl 2,6-dimethylpyridine-3,5-dicarboxylate, whi ch is the product of dehydrogenation of 1, identified by IR spectrosco py and mass spectrometry. The triplet state of C-60 is quenched by the Hantsch ester.