SYNTHESIS AND CHARACTERIZATION OF MIXED IODIDE-NAPHTHALENE COMPLEXES OF LANTHANIDES

Citation
Mn. Bochkarev et al., SYNTHESIS AND CHARACTERIZATION OF MIXED IODIDE-NAPHTHALENE COMPLEXES OF LANTHANIDES, Russian chemical bulletin, 45(10), 1996, pp. 2443-2444
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
10
Year of publication
1996
Pages
2443 - 2444
Database
ISI
SICI code
1066-5285(1996)45:10<2443:SACOMI>2.0.ZU;2-9
Abstract
The [LnI(2)(THF)(3)](2)(mu-C10H8) complexes were obtained by reactions of LnI(3)(THF)(3) (Ln = Ce, Pr, Nd, or Gd) with lithium and excess na phthalene. The magnetic moments of these complexes correspond to the o xidation state +3 of the metal atoms. The Yb-II complex, [YbI(DME)(2)] (2)(mu-C10H8), was synthesized by the reaction of YbI2(DME)(2) with an equimolar amount of naphthalenelithium.