BARRIERLESS DISCHARGE IN THE CONCENTRATED HCL SOLUTIONS AT HIGH-TEMPERATURES

Authors
KRIKSUNOV LB KRISHTALIK LI
Citation
Lb. Kriksunov et Li. Krishtalik, BARRIERLESS DISCHARGE IN THE CONCENTRATED HCL SOLUTIONS AT HIGH-TEMPERATURES, Journal of electroanalytical chemistry [1992], 354(1-2), 1993, pp. 99-103
Citations number
14
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
354
Issue
1-2
Year of publication
1993
Pages
99 - 103
Database
ISI
SICI code
Abstract
In 6 M HCl, at temperatures above about 80-degrees-C, the barrierless discharge of undissociated acid molecules has been observed. The effec tive transfer coefficient a is equal to approximately 1.2 at 80-degree s-C and decreases to 0.9 at 180-degrees-C. This trend is explained by the substantial influence of the phi1-potential on the barrierless dis charge of a neutral particle.