We have studied the initial stages ((1 divided-by 2) ML) of the growth
of Ag on Si(111) as a function of temperature T and deposition rate F
to identify the operating diffusion mechanism. The specular beam inte
nsity at 150 K shows short-lived oscillations which depend on the tota
l amount of Ag deposited, irrespectively of the deposition rate, and s
uggest the absence of thermal diffusion at this low temperature. Growt
h studies at higher temperatures T greater-than-or-equal-to 473 K, mon
itoring the formation of the square-root 3 x square-root 3 R30-degrees
structure as a function of deposition rate, measure a non-thermal com
ponent R0 > 50 angstrom to the diffusion length. The temperature depen
dence of the square-root 3 growth is used to measure an activation ene
rgy E(d) = (0.24 +/- 0.05) eV.