For Bi2Sr2CaCu2Oy (2212), it is shown that an oxygen gradient, as oppo
sed to a temperature gradient, can be used to produce large bulk forms
of the 2212 superconductor with highly textured microstructures from
an oxygen-deficient melt held at a constant temperature. Material prod
uced in this manner was found to have transition temperatures between
85 and 92 K, high critical current densities below 20 K, and modest cr
itical current densities at 77 K.